Michael C. Haibach

DiploPhos: A Hemilabile Bisphosphine for Sterically Hindered Ni-Catalyzed Suzuki–Miyaura Couplings

Abstract Pharmaceutically relevant Suzuki–Miyaura cross-couplings (SMCs) often require designer phosphine ligands and palladium loadings above 1 mol % to couple Lewis basic, sterically congested substrates. Recent work has demonstrated that nickel is an attractive alternative to...