Maurice van Gastel

Access to Unsupported Iminobismuthane and Tetraazabismole Species Enabled by a Rigid and Bulky Organobismuthinidene

ABSTRACT Herein, we report the reactivity of a monocoordinate bismuthinidene ( 1 ) with various organic azides. The reaction of 1 with p ‐toluenesulfonyl azide resulted in the formation of an unprecedented, unsupported iminobismuthane ( 2 ), which features the shortest reported B...