Masafumi Unno

From Molecular Cages to Functional Devices: Silsesquioxane Hybrid Platforms for Next-Generation Electronic Materials

Polyhedral oligomeric silsesquioxanes (POSS) and related silsesquioxanes provide an atomically precise platform for organic–inorganic hybrid electronics. Existing reviews mainly address synthesis, functionalisation, and application breadth; comparatively few connect molecular arc...

Hybrid Silk Fibroin/Poly(lactic acid) Macromer Nanogels for Advanced Drug Delivery: Influence of Organic and Silsesquioxane Crosslinker Topologies on Molecular Organization and Physicochemical Properties

Abstract Molecular orientation and structural topology play critical roles in determining the performance of biomacromolecular nanocarriers for controlled drug delivery. Herein, the influence of organic and silsesquioxane crosslinker topologies on hybrid nanogels composed of an a...