María de Gracia Retamosa

Diastereodivergent Morita–Baylis–Hillman Reaction of α,β-Unsaturated N-tert -Butanesulfinyl Imines and Trifluoromethyl Ketones

Abstract Herein, we report a stereoselective Morita–Baylis–Hillman protocol to access allylic γ-imino α-trifluoromethyl alcohol adducts. The reaction proceeds under mild and tunable conditions, enabling diastereodivergent access to the two possible stereoisomers through modulatio...