Marcus W. Drover

Flash Communication : Catching Platinum Red-Handed: Exhaustive Ligand Redistribution at a Tucked-In Iron Complex

Abstract Transmetalation conventionally entails the transfer of a single ligand (e.g., aryl, hydride, or alkyl) between two centers. Herein, we demonstrate a 3d-to-5d metal-to-metal transmetalation in which the iron center of an organometallic fulvene complex is formally replaced...