Manuel Kirchhof

Chiral Rh Diene NHC Complexes and Their Application in Rh-Catalyzed Cycloisomerization of Enynes

Abstract Chiral dienes and N-heterocyclic carbenes (NHC) are important ligands for transition-metal catalysis. Surprisingly, both ligand classes are rarely employed together in Rh complexes. To get more detailed insight into the interaction between NHC and diene ligand simultaneo...