Louise A. Berben

Observation of Weak Driving-Force Dependence of Hydride Formation with Iron Carbonyl Clusters

Abstract Metal-hydride formation reactions are common elementary reactions in catalytic systems, including fuel formation and organic transformations. Here, metal-hydride formation rates with metal carbonyl clusters [Fe4N(CO)12]− and [Fe5N(CO)15]− were determined in MeCN and aque...