Lorenzo Sorace

Spin Crossover in an Iron(II) Complex with a Radical Iminosemiquinonate Ligand

Abstract Metal complexes that exhibit spin crossover (SCO) or valence tautomerism (VT) are promising candidates for molecular materials. In an exploration of the interplay between SCO and VT in iron chemistry, we combined redox-active aminophenol derivatives (4,6-di-tert-butylphe...