Long‐Yong Xie

Sulfonium Salt‐Mediated Dithiocarbamation of Alkynes for Access to Dithiocarbamate‐Containing Z ‐Vinyl Sulfides

A practical and stereoselective method for the synthesis of vinyl sulfides bearing a dithiocarbamate moiety has been developed. The transformation proceeds via a sulfonium salt‐mediated difunctionalization of terminal alkynes using carbon disulfide (CS 2 ) and amines as readily a...