Lijia Wang

Biomimetic Fe(Pytacn)-Catalyzed Intramolecular C(sp3)–H Amination: Access to Heteroarene-Functionalized Sultams

Abstract A new Fe(Pytacn)-catalyzed intramolecular aliphatic C(sp3)–H amination system is reported for the first time via metal-nitrene-mediated C–H insertion. This protocol operates under mild room-temperature conditions, affording 20 structurally diverse sultams in up to 90% yi...