Kendal W. Southwell

Beyond the Oxo‐Wall: Synthesis and Reactivity of a Six‐Coordinate Formally Co IV ‐Oxo Complex

ABSTRACT Despite their implication in a number of oxidation processes, there is a paucity of well‐characterized high‐valent cobalt‐oxo complexes. In this study, we present the first example of a six‐coordinate formally Co(IV)‐oxo complex, [Co(TQA)(O)(OH)] + ( 1 , TQA = tris(2‐qui...