Kazutaka Shoyama

Dispersion‐Clamped Crystalline Supramolecular Columnar π‐Stacks of Adamantyl‐Substituted Pyrenes

ABSTRACT Despite their importance in supramolecular chemistry, zero‐offset columnar π‐stacks of polycyclic aromatic hydrocarbons (PAHs) are rarely observed in crystals because close cofacial packing is penalized by Pauli repulsion. Here we show a crystalline phase (CP) of adamant...