Jun Li

Sulfur-PassivatedSuperatomic Rh13S8± Clusterswith Enhanced Stability and UniqueElectronic Properties

Abstract Metal sulfides have attracted considerable attention in nanomaterials because of their unique properties supporting key applications in catalysis, energy storage, sensing and others. Thiol-protected metal clusters feature similar metal–sulfur bonding as in nanomaterials,...

A Heterogeneous Metal–LigandBifunctional Catalystfor Chemoselective Hydrogenation of α,β-Unsaturated Aldehydes

Abstract The concept of metal–ligand bifunctional catalysts has been extensively explored in homogeneous catalysis, yet it has not been reported in conventional heterogeneous catalysis. Inspired by the outer-sphere hydrogenation mechanism in homogeneous metal–ligand bifunctional...