Joseph A. Cotruvo

Near-Adjacent HeavyLanthanide Separation and SensingUsing Dimerizing Lanmodulins

Abstract Protein-based recovery, detection, and separation of rare earth elements (REs) have accelerated since the discovery of the lanmodulin (LanM) proteins. While exceptional at total RE recovery, prior proteins, like most ligands, exhibited limited ability to differentiate RE...

CircularlyPolarized Luminescence in Terbium-Lanmodulin:Disentangling the Effects of Primary Coordination Sphere and ChromophoreGeometry

Abstract The rational design of highly efficient circularly polarized luminescence (CPL) emitters requires a detailed understanding of the mechanisms governing chiroptical metrics. In particular, the ability to deconvolute the contributions from static and dynamic coupling is cri...