John Kouvetakis

Silane, Germane, and Stannane Activation by an Iron Dinitrogen Compound to Access Dimetallotetrylides

Abstract Upon adding Group 14 hydride gases to the recently prepared iron dinitrogen dimer, [(Triphos)Fe]2(μ-N2) (Triphos = H3CC(CH2PPh2)3), a generalized methodology for the preparation of diirontetrylides has been realized. The all-bond activation of SiH4 afforded the correspon...