John D. Holbrey

Weak Anion Hydration Drives LCST Behavior in Ionic Liquid–Water Mixtures: Insights from Calorimetry and Neutron Diffraction

Abstract Isothermal titration calorimetry (ITC) combined with neutron diffraction and isotopic substitution (NDIS) has been used to elucidate the molecular origins of lower critical solution temperature (LCST) behavior in the tetrabutylphosphonium 5-phenyltetrazolate/water ([P444...