Ji‐Jun Jiang

Cooperative Agostic‐Type C─H···Cu, Quadrupolar Cu···CO 2 , and C─H···O/π Interactions in an Ultra‐Microporous MOF Enable One‐Step Methane Purification From Quaternary C 3 H 8 /C 2 H 6 /CO 2 /CH 4

ABSTRACT While agostic‐type C─H···metal σ‐interactions are central to organometallic catalysis, their role in gas separation remains elusive. In this study, a robust phosphine‐functionalized ultra‐microporous Cu(I/II)‐organic framework, LIFM‐XYY‐15, featuring open metal sites (OM...