Jesús I. Mendieta‐Moreno

On-Surface Synthesis of a Low Bandgap Cyclopenta[ c , d ]azulene-Based Polymer

Abstract Nonbenzenoid topologies offer a compelling strategy to tailor the electronic properties of low-dimensional carbon materials. Here, we report the on-surface synthesis of a nonalternant polymer incorporating a [7–5–5] cyclopenta[c,d]azulene (CPA) motif on Au(111) via therm...

Inducing Radicality in Gold‐Coordinated Porphyrinoids Through Precise Tip‐Induced Covalent Bond Dissociation

π-Extended porphyrinoids are versatile platforms for the emerging field of π-electron magnetism in conjugated systems. However, achieving controlled bond-selective transformations that enable tuning of their electronic ground states remains a major challenge. Here, we propose a p...

Inducing Radicality in Gold‐Coordinated Porphyrinoids Through Precise Tip‐Induced Covalent Bond Dissociation

ABSTRACT π‐Extended porphyrinoids are versatile platforms for the emerging field of π‐electron magnetism in conjugated systems. However, achieving controlled bond‐selective transformations that enable tuning of their electronic ground states remains a major challenge. Here, we pr...