Jacob L. Brownlee

Rare‐Earth Multivariate Metal–Organic Frameworks: Cationic Radius Biased Compositional Control and Property Tuning

ABSTRACT The synthesis of a multivariate metal–organic framework (MTV‐MOF) family, [Ln(DNNDI) 1.5 ] n ( UoB‐116 ), is reported (DNNDI: N , N' ‐bis(dinicotinate)‐1,4,5,8‐naphthalenetetracarboxydiimide). UoB‐116(Ln) is formed by 15 different metals (Ln = Y, La, Ce, Pr, Nd, Sm, Eu,...

Rare‐Earth Multivariate Metal–Organic Frameworks: Cationic Radius Biased Compositional Control and Property Tuning

ABSTRACT The synthesis of a multivariate metal–organic framework (MTV‐MOF) family, [Ln(DNNDI) 1.5 ] n ( UoB‐116 ), is reported (DNNDI: N , N' ‐bis(dinicotinate)‐1,4,5,8‐naphthalenetetracarboxydiimide). UoB‐116(Ln) is formed by 15 different metals (Ln = Y, La, Ce, Pr, Nd, Sm, Eu,...