Jacob Green

Nitrene-Transfer Chemistry to Olefins Mediated by Co(III) Catalysts Supported by a Tetraamido Macrocycle

Abstract A tetraamido macrocyclic ligand scaffold (L1H4) has been synthesized and metalated with Co(III) to afford anionic metal complexes [CoIII(L1)]− (cations: K+, PPh4+) that are paramagnetic (S = 1) in solution and display semi-reversible reduction waves (CoII/III) and irreve...