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Site-Selective Fe Incorporation in Layered Polar α-In2Se3: Crystal-Chemical Control of Localized Spin States and Ferroic Responses

Abstract Site-selective transition-metal incorporation provides a crystal-chemical route for tuning local bonding, spin states, and ferroic responses in layered inorganic chalcogenides. Here, Fe-incorporated α-In2Se3 is investigated to clarify how Fe site preference and spatial d...

Mixed-Connectivity GeS4 Framework for Wavelength-Dependent Linear Dichroism in Layered GeS2

Abstract Polyhedral connectivity offers a crystal-chemical route for understanding anisotropic properties in low-symmetry solids. Here, layered monoclinic GeS2 is investigated as a mixed-connectivity tetrahedral system composed of corner-sharing Ge−S−Ge bridges and edge-sharing G...