Hong‐Bo Qin

Total Synthesisof (±)-Caryopincaolide A

Abstract The first total synthesis of (±)-caryopincaolide A, a rearranged abeo-abietane diterpenoid containing a 5/6/6 fused skeleton and three contiguous all-carbon quaternary centers, is described. The route installs the aromatic ring at an early stage and assembles the congest...