Hiroyuki Kishimoto

Hierarchical Electronic Transport in Giant Mixed-Valence {Mo154} Rings Revealed in Anhydrous Single-Molecule-Layer Networks

Abstract Polyoxometalates (POMs) are redox-active metal–oxo clusters of central interest in molecular and materials chemistry. The giant mixed-valence {Mo154} ring, built from 14 repeating subunits, is a prototypical system expected to exhibit rich electronic functionality; howev...