Heyun Sheng

Photocatalyst-Free Visible-Light-Mediated Synthesis of β-(Trifluoromethyl)alkenyl Ketoximes Using 2-Bromo-3,3,3-trifluoropropene as a Radical Precursor

Abstract We report a photocatalyst-free, visible-light-mediated difunctionalization of alkenes employing 2-bromo-3,3,3-trifluoropropene (BTP) as a radical precursor. This protocol operates under mild conditions using potassium formate as an electron transfer reagent and tert-buty...