Haojie Tian

Photo‐Enhanced Electronic Metal–Support Interaction Boosts Low‐Temperature Water–Gas Shift Reaction via Ni δ+ –O V –Ce 3+ Interfacial Redox Cycling

ABSTRACT Nickel (Ni) is an attractive non‐noble‐metal catalyst for the water‐gas shift reaction (WGSR), yet strong CO adsorption and competing methanation severely limit its activity and selectivity. Herein, we develop a series of NiCe layered double hydroxide‐derived catalysts (...

Catalytic Insertion of Pd–Vinylidenes Into B─H Bonds

ABSTRACT An unprecedented palladium (Pd)‑catalyzed insertion of unsaturated carbenes into B─H bonds is described. Using alkynyl hypervalent iodine reagents as carbene precursors and amine–borane adducts as boron sources, this method delivers a broad range of E ‑configured alkenyl...