Hai‐Ming Guo

Electrochemical Synthesis of Macrocyclic Iminoisocoumarins by Rh-Catalyzed Intramolecular Vinylic C–H Activation/Heterocyclization

Abstract Herein, we report a new macrocyclization strategy via electrochemical Rh(III)-catalyzed intramolecular vinylic C–H activation and subsequent heterocyclization. This approach affords diverse iminoisocoumarin-braced macrocycles with 13- to 28-membered rings bearing various...