Gwanggyun Kim

Stereoselective 1,2-Metalate Rearrangement of α-Chloroalkylboronic Esters with gem -Diborylalkanes

Abstract Highly diastereoselective 1,2-metalate rearrangements of α-haloalkylboronic esters that simultaneously construct contiguous stereogenic centers remain limited. Herein, we report a highly diastereoselective and stereospecific 1,2-metalate rearrangement of enantioenriched...