Guo‐Yu Yang

V-Shaped {Cu8}-Added Polyoxometalate for Visible-Light-Driven Hydrogen Evolution and Photothermal Conversion

Abstract A {Cu8}-added polyoxometalate (Cu8AP), H3Cs13[CuB(OH)3(GeW6O26)Cu8(H2O)2(GeW9O34)2]·2Cl·15H2O (1), was synthesized via the lacunary directing synthetic strategy. Visible-light-driven photocatalytic H2 evolution performance revealed an exceptional evolution rate of 12632....

Metallomacrocyclic Ligands Stabilized Icosahedral Superatomic Nanoclusters With NIR‐I to NIR‐II Phosphorescence Modulation

ABSTRACT Coinage metal nanoclusters with near‐infrared‐II (NIR‐II, λ PL > 1000 nm) photoluminescence hold great promise for biological applications. Here, we report the first icosahedral M 13 cluster exhibiting NIR‐II phosphorescence, achieved through an unprecedented metallom...