Guisheng Zhang

DehydroxylativeCross-Electrophile Coupling of AromaticAcids with Glycosyl Chlorides Enables Rapid C -AcylGlycoside Synthesis

Abstract We disclose a synergistic nickel/photoredox/phosphoranyl radical catalytic platform for the cross-electrophile coupling of aromatic acids with glycosyl chlorides, affording structurally diverse C-acyl glycosides in a stereoselective manner directly from unactivated carbo...

Metal-Free Disulfonylationof Terminal Allenes

Abstract A facile and efficient metal-free protocol for the highly regio- and stereoselective disulfonylation of terminal allenes has been established herein, which enables the straightforward synthesis of structurally diverse (E)-1,2-disulfonyl allylic derivatives in satisfactor...