Gregor Schnakenburg

Light-Enhanced Synthesis of TiSb2 and TiBi2 Metallacycles

Abstract The synthesis of small metallacycles of early transition metals and heavy pnictogens has been primarily achieved by reductive coupling of the pnictane moiety with a transition metal fragment. Herein, we report a light-enhanced synthesis of titanocene Sb2 and Bi2 metallac...

Iron‐Photocatalyzed Alkene Chloroaminoxylation: A Platform for Orthogonally Activatable Building Blocks

ABSTRACT We report the development of an iron‐photocatalyzed 1,2‐chloroaminoxylation of alkenes that installs two orthogonal and independently activatable synthetic handles, a chlorine atom and an alkoxyamino group, across a diverse range of alkene substrates. The reaction is dri...