Giacomo Di Giambattista

Sequence‐Controlled Copolymers Through Selective Ring‐Opening Polymerization of Multiunit Macrolactones

ABSTRACT A new strategy for the synthesis of sequence‐controlled polymers (SCP), in which increased ester reactivity by the introduction of neighboring glycolate units within a multiunit macrolactone, was developed. DFT calculations and model reactions show that the proximity of...