Frank W. Heinemann

Air- and Thermally Stable Organometallic Fe(VI) Nitrides Enabled by a Tripodal Mesoionic Carbene Ligand: Access to a Water-Coordinated Fe(VI) Nitrido Complex

Abstract A tripodal mesoionic carbene (MIC) ligand, tris-[4-(1-mesityl-3-methyl-1,2,3-triazol-5-ylidene)methyl]amine (TAMNMes), enables the synthesis and isolation of a family of exceptionally robust organometallic Fe(VI) nitrido complexes. One-electron oxidation of the correspon...

Chemically Induced Spin-Crossover in an Iron(II) Bis(Pyrazol-1-yl)pyridine-Based Complex in Solution

Abstract Bis(pyrazol-1-yl)pyridine (1-BPP)-based iron(II) spin-crossover complexes have been widely investigated in the solid state. However, the application of such systems in the solution phase remains challenging. Here, we report a series of boronic acid-featured 1-BPP iron(II...