Author
Francesco Cirigliano
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Recent research
- Materials & EnergyOpen access
NHC‐Copper(I)‐Mediated Functionalization of White Phosphorus
ABSTRACT We report a method for converting white phosphorus (P 4 ) directly into tetra‐ and pentaphosphanes using N ‐heterocyclic carbene (NHC) copper(I) complexes. The insertion of P 4 into the metal‐element bonds of the NHC complexes (6Dipp)Cu(Nu) [Nu = O t Bu and N( i Pr) 2 ]...