Dietmar Stalke

Tailoring Reactivity of Molecular Gallium Hydroxides via Chalcogen Bridging

Abstract We studied the influence of bridging chalcogen atoms (μ-E; E = S, Se) on the structure and reactivity of digallium dihydroxide complexes [{MeLGa(OH)}2(μ-E)] [E = S (4), Se (5); MeL = CH{CMe(NAr)}2–, Ar = 2,4,6-Me3C6H2]. Compounds 4 and 5 were synthesized from MeLGaCl2 an...