Di Sun

Thermally Reversible Transformation between Two Isomers of Silver Sulfide Magic-Size Clusters

Abstract Isomers of semiconductor magic-size clusters (MSCs) share the same molecular formula but can exhibit distinct optical and electronic properties. Most of the reported MSC isomers have been so far limited to cadmium chalcogenides. Herein, we report the reversible transform...

Thermally Activated Delayed Fluorescence (TADF) in Coinage Metal Nanoclusters: Bridging Molecular and Nanoscopic Photophysics

Abstract Thermally activated delayed fluorescence (TADF) in coinage metal nanoclusters (CMNCs) has introduced new paradigms in the design of optoelectronic materials, uniting atomic precision with tunable quantum and photophysical properties. This review provides a critical and c...

Fluorite‐Type Silsesquioxane‐Protected Cerium Cluster as Molecular Analog of Highly Reduced Nanoceria Fragment for Efficient Photocatalysis

ABSTRACT The surface oxygen vacancy defects generated from the abstraction of lattice oxygen atoms of bulk ceria accompanied by the reduction of Ce IV to Ce III , are considered to play a pivotal role in photocatalysis. As ideal molecular models of nanoceria, atom‐precise cerium‐...