D.G. Golovanov

Effect of Structural Motif on Magnetic Properties in Molybdenum Chlorides of Mo5+ Ions: Ferromagnetism from Mo2Cl10 Dimers and Antiferromagnetism from Isolated MoCl6– Anions

Abstract The evolution of magnetic properties in molybdenum chloride systems caused by structural motif changes was investigated by magnetic property measurements and DFT calculations. In ξ-MoCl5, characterized by the presence of molybdenum dimers, the formation of ferromagnetic...