Deesha D. Malik

A Negative Temperature Effect on the Reversible Conversion between Redox Tautomers of CoIII(OH) and CoIV(O) Complexes Bearing a Redox-Non-Innocent Tetraamido Macrocyclic Ligand

Abstract Elucidating highly reactive intermediates in catalytic reactions relies heavily on cryogenic trapping techniques, where intermediates observed in solution are generally assumed to remain unchanged upon flash-freezing at 77 K. Herein, we demonstrate a striking exception t...