Daria Boglaienko

Comprehensive Experimental and Computational Spectroscopic Study of Electronic Coupling in Solvated Mixed Valence Multimetal Complexes Using Photons from the IR through X-rays

Abstract We present a comprehensive experimental and computational spectroscopic study of the trinuclear cyanide-bridged mixed-valence complex trans-[RuIIL4{(μ-NC)FeIII(CN)5}2]4– (FeRuFe), where L = pyridine or 4-methoxypyridine dissolved in methanol and water. Four complementary...