Daniel Roth

Enantiodivergent Carbon–PhosphorusBond Formationvia Enzymatic Carbene Insertion

Abstract Phosphorus is one of the six elements of life, yet enzymatic carbon–phosphorus (C–P) bond formation is exceedingly rare in nature. This gap in the biosynthetic toolkit is particularly consequential, given the prominence of stereogenic-at-phosphorus P(V) scaffolds in phar...