Daiki Shimizu

Pd(II)-Templated End-to-End Cyclization of Doubly N-Confused Bilatrienes: A Stable Singlet Diradicaloid Dye with Efficient Absorption across the Solar Spectrum

Abstract We report a highly stable singlet diradicaloid (Pd1-dimer), formed through a Pd(II)-templated end-to-end cyclization of a linear N-confused bilatriene (1). This unique Pd-bridged double-loop complex exhibits an open-shell singlet diradicaloid ground state with an extreme...