Bhuvnesh Singh

Enantioselective Pericyclization of Naphthol-Substituted Alkynyl Ketimines

Abstract A vinylidene ortho-quinone methide (VQM)-mediated, organocatalyzed tandem 6π-azaelectrocyclization and dearomatizing spirocycloaddition of naphthol-substituted alkynyl ketimines, facilitated by NBS, have been realized. This strategy enables the enantioselective synthesis...