Aurelio Gallardo

Inducing Radicality in Gold‐Coordinated Porphyrinoids Through Precise Tip‐Induced Covalent Bond Dissociation

π-Extended porphyrinoids are versatile platforms for the emerging field of π-electron magnetism in conjugated systems. However, achieving controlled bond-selective transformations that enable tuning of their electronic ground states remains a major challenge. Here, we propose a p...

Inducing Radicality in Gold‐Coordinated Porphyrinoids Through Precise Tip‐Induced Covalent Bond Dissociation

ABSTRACT π‐Extended porphyrinoids are versatile platforms for the emerging field of π‐electron magnetism in conjugated systems. However, achieving controlled bond‐selective transformations that enable tuning of their electronic ground states remains a major challenge. Here, we pr...

Tunable Oxygen Connectivity in Carbaporphyrinoid Polymers on Metal Surfaces

ABSTRACT Controlling oxygen‐mediated connectivity at metal surfaces offers a powerful route to engineer covalent and metal–organic architectures with atomic precision. Here, we demonstrate tunable oxygen‐based connectivity in carbaporphyrinoid polymers on Au(111) under ultrahigh...