Antonio Martı́n

A Diamagnetic Six-Coordinate Ag(III) Complex

Abstract The octahedral complex AgIII(CF3)3tpy (2Ag), attainable from AgIII(CF3)3py (1Ag) and terpyridine (tpy), has been isolated and characterized using NMR spectroscopy and Sc-XRD. Strikingly, 2Ag proved to be diamagnetic and showed tridentate coordination of the tpy ligand, t...