Anthony Cozzolino

σ-Hole Engineering Enables Selective Supramolecular Isomer Formation in Sb(III) Hosts

Abstract Pnictogen bonding (PnB) has emerged as a directional and tunable noncovalent interaction, yet the presence of multiple σ-holes on trivalent pnictogen centers introduces a question: can individual σ-holes be selectively addressed for binding, and do their relative reactiv...