Author
Anna Zens
Recent research
- Materials & EnergyOpen access
Chiral Rh Diene NHC Complexes and Their Application in Rh-Catalyzed Cycloisomerization of Enynes
Abstract Chiral dienes and N-heterocyclic carbenes (NHC) are important ligands for transition-metal catalysis. Surprisingly, both ligand classes are rarely employed together in Rh complexes. To get more detailed insight into the interaction between NHC and diene ligand simultaneo...
- Materials & EnergyOpen access
ABSTRACT In this work, a series of novel unsymmetrical fluorenone derivatives bearing various head groups (H, Br, NO 2 , NH 2 , and CN) was synthesized and investigated with respect to their mesomorphic and photophysical properties. Depending on the head group, SmA, N, or SmC pha...