Andreas Scheurer

Air- and Thermally Stable Organometallic Fe(VI) Nitrides Enabled by a Tripodal Mesoionic Carbene Ligand: Access to a Water-Coordinated Fe(VI) Nitrido Complex

Abstract A tripodal mesoionic carbene (MIC) ligand, tris-[4-(1-mesityl-3-methyl-1,2,3-triazol-5-ylidene)methyl]amine (TAMNMes), enables the synthesis and isolation of a family of exceptionally robust organometallic Fe(VI) nitrido complexes. One-electron oxidation of the correspon...