Abhinav Sai Chalasani

Hammett-Driven Secondary Ligand Effects Control Geometry and Electronic Structure of 5-Substituted Copper(II)–Cytosine Complexes

Abstract Metal-nucleobase interactions play central roles in biological chemistry and metal-based therapeutic design, yet the influence of nucleobase substitution on coordination geometry and thermodynamic stability remains underexplored. Herein, we report the systematic investig...