Aaron M. Tondreau

Phosphine Coordination to Ce, Nd, Np, and Pu in Ar BiAMP t Bu ‐Supported Complexes and Their 2 H and 13 C Isotopologues

ABSTRACT 13 C‐ and 2 H‐enriched bis((3,5‐dimethylphenyl)aminomethyl) tert butylphosphine (the natural abundance (NA) ligand Ar BiAMP t Bu ; the 2 H‐ and 13 C‐labelled analogues are denoted as d 4 ‐ Ar BiAMP t Bu and 13 C 2 ‐ Ar BiAMP t Bu , respectively), containing two secondary...

Synthesis Notes on Generating Bimetallic 243Am Complexes Using Inherent Lewis Acidity and the TPT Cryptand

Abstract Tris(pyridinediimine)bis(tren) (TPT) was employed as a proligand in reactions with 243Am(NO3)3·nH2O in methanol generating several product types consistent with observations from analogous reactions with the lanthanide series. [Am(TPT)][Am(NO3)6] (1) was identified along...